منابع مشابه
Iridium-Catalyzed Arylative Cyclization of Alkynones by 1,4-Iridium Migration**
1,4-Metal migrations enable the remote functionalization of C-H bonds, and have been utilized in a wide variety of valuable synthetic methods. The vast majority of existing examples involve the 1,4-migration of palladium or rhodium. Herein, the stereoselective synthesis of complex polycycles by the iridium-catalyzed arylative cyclization of alkynones with arylboronic acids is described. To our ...
متن کاملSynthesis of new heteroscorpionate iridium(I) and iridium(III) complexes.
The reactivity of different heteroscorpionate ligands based on bis(pyrazol-1-yl)methane, with different iridium-(i) and -(iii) precursors is reported. The reaction of the heteroscorpionate lithium salts "Li(bdmpza)", [bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate], "Li(bdmpzdta)" [bdmpzdta = bis(3,5-dimethylpyrazol-1-yl)dithioacetate] and "Li(S)-mbpam" [(S)-mbpam = (S)-(-)-N-α-methylbenzyl-2,2-...
متن کاملVi-1 Vi. Suffix Dictionaries
Cosine Numeric Abstract, Cosine Logical Abstract, Overlap Logical Overlap Logical Abstract, Cosine Numeric Cosine Numeric Text, Cosine Numeric Text, Cosine Logical Text, Overlap Logical Abstract, Cosine Numeric Cosine Numeric Abstract, Cosine Logical Cosine Logical Title, Cosine Numeric EVALUATION MEASURE Normed. Recall Normed. Precision Normed. Recall Normed. Precision Normed. Recall Normed. P...
متن کاملIridium–catalyzed 1,3–dipolar cycloadditions
1,3–Dipolar cycloaddition reactions (DCR) are atom–economic processes that permit the construction of heterocycles. Their enantioselective versions allow for the creation of up to four adjacent chiral centers in a concerted fashion. In particular, well–defined half–sandwich iridium (III) catalysts have been applied to the DCR between enals or methacrylonitrile with nitrones. Excellent yield and...
متن کاملLaser spectroscopy of iridium monoboride.
High resolution laser induced fluorescence spectrum of IrB in the spectral region between 545 and 610 nm has been recorded and analyzed. Reacting laser-ablated iridium atoms with 1% B(2)H(6) seeded in argon produced the IrB molecule. This is the first experimental observation of the IrB molecule. Four vibronic transition bands, (v,0) with v=0-3 of an electronic transition system, have been obse...
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1930
ISSN: 0369-4208,2185-0909
DOI: 10.1246/nikkashi1921.51.189